Change of the ambient particle size distribution in East Germany between 1993 and 1999

Size distribution of particle number concentrations in the geometric equivalent diameter range 0.01-2.5 mum were determined in three communities, Zerbst, Bitterfeld and Hettstedt of the state of Sachsen-Anhalt in Eastern Germany, in the first half of 1993 and 1999. A Mobile Aerosol Spectrometer (MAS) consisting of a differential mobility particle spectrometer (DMPS) and a laser aerosol spectrometer (LAS-X) were used for size-selective particle number concentration measurements from which mass concentrations were derived based on an apparent mean density of the ambient aerosol of the closely situated city of Erfurt. The total number concentration was governed by ultra-line particles (<0.1 mum) (81% in 1993 and 90% in 1999) and 0.1-0.5 mum size fraction dominates total mass concentration (approximately 80%). While the mass concentration of fine particles (PM2.5) decreased from 39 to 19 mug m(-3), the geometric means of total number concentration showed constant concentration (13.3 x 10(3) cm(-3) in 1993 and 13.3 x 10(3) cm(-3) in 1999, P = 0.975) and the geometric means of number concentration of ultra-fine particles (UP) between 10 and 30 nm increased from 5.9 x 10(3) to 8.2 x 10(3) cm(-3) from 1993 to 1999 (p = 0.016). The temporal changes of number and mass concentrations in the three communities are similar, The clear shift to smaller particle sizes within this six years period was caused by changes of the most prominent sources, traffic and domestic heating, since formerly dominating industries in Bitterfeld and Hettstedt had vanished grossly. (C) 2001 Elsevier Science Ltd. All rights reserved.