Stretchable Graphene: A Close Look at Fundamental Parameters through Biaxial Straining

被引:313
作者
Ding, Fei [1 ,3 ]
Ji, Hengxing [1 ]
Chen, Yonghai [3 ]
Herklotz, Andreas [2 ]
Doerr, Kathrin [2 ]
Mei, Yongfeng [1 ]
Rastelli, Armando [1 ]
Schmidt, Oliver G. [1 ]
机构
[1] IFW Dresden, Inst Integrat Nanosci, D-01069 Dresden, Germany
[2] IFW Dresden, Inst Metall Mat, D-01069 Dresden, Germany
[3] Chinese Acad Sci, Inst Semicond, Key Lab Semicond Mat Sci, Beijing 100083, Peoples R China
关键词
Graphene; strain engineering; Gruneisen parameters; Raman spectroscopy; piezoelectric actuator; RAMAN-SPECTROSCOPY; MONOLAYER; SUBSTRATE; TRANSPORT;
D O I
10.1021/nl101533x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tunable biaxial stresses, both tensile and compressive, are applied to a single layer graphene by utilizing piezoelectric actuators. The Gruneisen parameters for the phonons responsible for the D, G, 2D and 2D' peaks are studied. The results show that the D peak is composed of two peaks, unambiguously revealing that the 2D peak frequency (omega(2D)) is not exactly twice that of the D peak (omega(D)). This finding is confirmed by varying the biaxial strain of the graphene, from which we observe that the shift of omega(2D)/2 and omega(D) are different. The employed technique allows a detailed study of the interplay between the graphene geometrical structures and its electronic properties.
引用
收藏
页码:3453 / 3458
页数:6
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