Homogeneous supported synthesis using ionic liquid supports: Tunable separation properties

被引:69
作者
Handy, ST [1 ]
Okello, M [1 ]
机构
[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
关键词
D O I
10.1021/jo047807k
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We report a homogeneous supported version of Koser's salt based on a room-temperature ionic liquid (RTIL) support. By altering the nature of the RTIL, a material was developed that was stable, recyclable, and readily separable from the tosyloxylated ketone products just by using variations in solvent polarity. A similar approach should be applicable to a wide range of supported catalysts and reagents.
引用
收藏
页码:2874 / 2877
页数:4
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