Heterocyclic heptamers containing thiophene and pyrrole units: Synthesis and properties

被引:46
作者
Parakka, JP [1 ]
Jeevarajan, JA [1 ]
Jeevarajan, AS [1 ]
Kispert, LD [1 ]
Cava, MP [1 ]
机构
[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487
关键词
D O I
10.1002/adma.19960080110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Studies on septithiophenes are relatively rare compared to the available detailed investigations of sexithiophenes. The balance is redressed here by a report of the synthesis, electrochemistry and spectroscopic properties of a new alpha,omega-disubstituted septithiophene and two pyrrole-containing septithiophene analogues. Two different routes are described by which it was attempted to impart solubility in organic solvents to septithiophenes-one unsuccessful and one successful. Evidence of an unusual three-electron transfer process is also presented.
引用
收藏
页码:54 / &
页数:7
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