Rate of cyclization of perfluoro-4-oxa-5-hexenyl radical. Use of tributylgermanium hydride as an effective H-transfer agent for perfluoro-n-alkenyl radicals

被引：21

作者：

Dolbier, WR

Rong, XX

Smart, BE

Yang, ZY

机构：

[1] DUPONT CO INC,CENT RES & DEV,EXPTL STN,WILMINGTON,DE 19880

[2] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 14期

关键词：

D O I：

10.1021/jo960395y

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[No abstract available]

引用

页码：4824 / 4826

页数：3

共 19 条

[1] ABSOLUTE RATE CONSTANTS FOR SOME REACTIONS OF PERFLUORO-N-ALKYL RADICALS IN SOLUTION [J].

AVILA, DV ;

INGOLD, KU ;

LUSZTYK, J ;

DOLBIER, WR ;

PAN, HQ ;

MUIR, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (01) :99-104

[2] RELATIVE REACTIVITIES OF VARIOUS SULFIDES, SELENIDES AND HALIDES TOWARDS SH2 ATTACK BY TRIBUTYLGERMYL RADICALS [J].

BECKWITH, ALJ ;

PIGOU, PE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (07) :1151-1155

[3] DETERMINATION OF THE RATES OF RING-CLOSURE OF OXYGEN-CONTAINING ANALOGS OF HEX-5-ENYL RADICAL BY KINETIC ELECTRON-SPIN-RESONANCE SPECTROSCOPY [J].

BECKWITH, ALJ ;

GLOVER, SA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1987, 40 (01) :157-173

[4] REGIO-SELECTIVITY AND STEREO-SELECTIVITY OF ALKENYL RADICAL RING-CLOSURE - A THEORETICAL-STUDY [J].

BECKWITH, ALJ ;

SCHIESSER, CH .

TETRAHEDRON, 1985, 41 (19) :3925-3941

[5]

CARLSON D, COMMUNICATION

[6] ABSOLUTE RATE CONSTANTS FOR THE ADDITION OF TRIETHYLSILYL RADICALS TO VARIOUS UNSATURATED-COMPOUNDS [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (10) :3292-3296

[7] RATE CONSTANTS FOR THE REACTIONS OF TRIS(TRIMETHYLSILYL)SILYL RADICALS WITH ORGANIC HALIDES [J].

CHATGILIALOGLU, C ;

GRILLER, D ;

LESAGE, M .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (10) :2492-2494

[8] KINETIC EFFECTS OF FLUORINE SUBSTITUENTS IN FREE-RADICAL CHEMISTRY - HYDROGEN-ATOM ABSTRACTION REACTIONS OF PERFLUORO-N-ALKYL RADICALS [J].

DOLBIER, WR ;

RONG, XX .

JOURNAL OF FLUORINE CHEMISTRY, 1995, 72 (02) :235-240

[9]

DOLBIER WR, 1994, TETRAHEDRON LETT, V34, P6225

[10] ABSOLUTE RATE CONSTANTS FOR THE REACTIONS OF TRI-NORMAL-BUTYLGERMYL AND TRI-NORMAL-BUTYLSTANNYL RADICALS WITH CARBONYL-COMPOUNDS, OTHER UNSATURATED MOLECULES, AND ORGANIC HALIDES [J].

INGOLD, KU ;

LUSZTYK, J ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (02) :343-348

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