Improved enantioselective dihydroxylation of bishomoallylic alcohol derivatives using a mechanistically inspired bis-cinchona alkaloid catalyst

被引：27

作者：

Corey, EJ

Noe, MC

Ting, AY

机构：

[1] Department of Chemistry, Harvard University, Cambridge

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 11期

关键词：

D O I：

10.1016/0040-4039(96)00163-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic dihydroxylation of p-methoxybenzoate esters of various bishomoallylic alcohols proceeds with excellent enantioselectivity and in the case of diolefins, with improved regioselectivity using a designed catalyst that incorporates an N-anthracenylmethyl group to enhance catalyst-substrate binding interactions.

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页码：1735 / 1738

页数：4

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