Solute-solvent and solvent-solvent interactions evaluated through clusters isolated from solutions: Preferential solvation in water-alcohol mixtures

被引：119

作者：

Wakisaka, A

Komatsu, S

Usui, Y

机构：

[1] Natl Inst Resources & Environm, Tsukuba, Ibaraki 3058569, Japan

[2] Ibaraki Univ, Mito, Ibaraki 3108512, Japan

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2001年 / 90卷 / 1-3期

关键词：

D O I：

10.1016/S0167-7322(01)00120-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mass spectrometric analysis of clusters in alcohol (methanol, ethanol, l-propanol)-water binary mixtures provided information on the microscopic structures of these binary mixtures at the cluster level. Preferential solvation for the hydrophobic substrates by the alcohol molecules in the alcohol-water mixtures was found to be promoted by the alcohol self-aggregation in the solution. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：175 / 184

页数：10

相关论文

共 13 条

[1]

BERLMANN JB, 1971, HDB FLUORESCENCE SPE, P408

[2] Low-frequency Raman spectroscopy of ethanol-water binary solution: Evidence for self-association of solute and solvent molecules [J].

Egashira, K ;

Nishi, N .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (21) :4054-4057

[3] CORRELATION OF SOLVOLYSIS RATES .3. TERT-BUTYL CHLORIDE IN A WIDE RANGE OF SOLVENT MIXTURES [J].

FAINBERG, AH ;

WINSTEIN, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (12) :2770-2777

[4] Preferential solvation studied by the fluorescence lifetime of acridine in water-alcohol mixtures [J].

Ito, O ;

Ito, E ;

Yoshikawa, Y ;

Watanabe, A ;

Kokubun, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (02) :227-230

[5] THE EFFECT OF SOLVENT ON SPECTRA .1. A NEW EMPIRICAL MEASURE OF SOLVENT POLARITY - Z-VALUES [J].

KOSOWER, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (13) :3253-3260

[6] Preferential solvation studied by the fluorescence spectrum of pyrene in water-alcohol binary mixtures [J].

Kusumoto, Y ;

Takeshita, Y ;

Kurawaki, J ;

Satake, I .

CHEMISTRY LETTERS, 1997, (04) :349-350

[7] STRUCTURE OF CLUSTERS IN ETHANOL-WATER BINARY-SOLUTIONS STUDIED BY MASS-SPECTROMETRY AND X-RAY-DIFFRACTION [J].

MATSUMOTO, M ;

NISHI, N ;

FURUSAWA, T ;

SAITA, M ;

TAKAMUKU, T ;

YAMAGAMI, M ;

YAMAGUCHI, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (07) :1775-1783

[8] CONVERSION OF LIQUIDS TO CLUSTER BEAMS BY ADIABATIC EXPANSION OF LIQUID JETS - MASS-SPECTROMETRIC ANALYSIS OF MOLECULAR ASSOCIATION IN AQUEOUS-SOLUTION SYSTEMS [J].

NISHI, N ;

YAMAMOTO, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (24) :7353-7361

[9] Non-ideality of binary mixtures - Water-methanol and water-acetonitrile from the viewpoint of clustering structure [J].

Wakisaka, A ;

Abdoul-Carime, H ;

Yamamoto, Y ;

Kiyozumi, Y .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (03) :369-374

[10] Molecular self-assembly controlled by acid-base non-covalent interactions: A mass spectrometric study of some organic acids and bases [J].

Wakisaka, A ;

Akiyama, Y ;

Yamamoto, Y ;

Engst, T ;

Takeo, H ;

Mizukami, F ;

Sakaguchi, K ;

Jones, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (19) :3539-3544