Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3Cu(NCMe)

被引：141

作者：

Díaz-Requejo, MM

Belderraín, TR

Nicasio, MC

Trofimenko, S

Pérez, PJ

机构：

[1] Univ Huelva, Dept Quim & Ciencia Mat, Huelva 21071, Spain

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 40期

关键词：

D O I：

10.1021/ja037072l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex TpBr3Cu(NCMe) catalyzes, at room temperature, the insertion of a nitrene group from PhINTs into the carbon-hydrogen bond of cyclohexane and benzene, as well as into the primary C-H bonds of the methyl groups of toluene and mesitylene, in moderate to high yield. Copyright © 2003 American Chemical Society.

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页码：12078 / 12079

页数：2

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