Microfluidic chip for electrochemically-modulated liquid|liquid extraction of ions

被引：39

作者：

Berduque, Alfonso ^{[1
]}

O'Brien, Joseph ^{[1
]}

Alderman, John ^{[1
]}

Arrigan, Damien W. M. ^{[1
]}

机构：

[1] Natl Univ Ireland Univ Coll Cork, Tyndall Natl Inst, Cork, Ireland

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 01期

基金：

爱尔兰科学基金会;

关键词：

microfluidics; ITIES; laminar flow; ion transfer; extraction;

D O I：

10.1016/j.elecom.2007.10.023

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 [应用化学];

摘要：

A microfluidic device with integrated electrodes for the electrochemically-modulated extraction of ions across immiscible aqueous-organic liquid-liquid interfaces is presented. Using a Y-shaped microfluidic channel with in situ electrodes and co-flowing aqueous and organic immiscible electrolyte solutions, the manipulation of the applied interfacial potential enabled the extraction of ions from the aqueous phase into the organic phase. Data for the extraction of tetraethylammonium cations from aqueous electrolyte into 1,2-dichloroethane electrolyte are presented. The device demonstrates the benefits of combination of microfluidics and liquid-liquid electrochemistry. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：20 / 24

页数：5

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