Grey model (GM) and artificial neural network (ANN) were employed to predict suspended solids (SSeff), chemical oxygen demand (CODeff) and pH(eff) in the effluent from conventional activated process of an industrial wand pH, astewater treatment plant using simple online monitoring parameters (pH in the equalization pond effluent; pH, temperature, and dissolved oxygen in the aeration tank). The results indicated that the minimum mean absolute percentage errors of 20.79, 6.09 and 0.71% for SSeff, CODeff and pH(eff), respectively, could be achieved using different types of GMs. GM only required a small amount of data (at least four data) and the prediction results were even better than those of ANN, According to the results, the online monitoring parameters could be applied on the prediction of effluent quality. It also revealed that GM could predict the industrial effluent variation as its effluent data was insufficient. (c) 2007 Elsevier Ltd. All rights reserved.