A facile preparation of 3-haloflavones using hypervalent iodine chemistry

被引:28
作者
Rho, HS
Ko, BS
Ju, YS
机构
[1] Pacific Corp, Dept Appl Skin Biol, Yongin Si 449900, Kyounggi Do, South Korea
[2] Korea Inst Oriental Med, Seoul 135100, South Korea
[3] Woosuk Univ, Coll Oriental Med, Jeonju, South Korea
关键词
D O I
10.1081/SCC-100104459
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Various 3-haloflavones were prepared by the reaction of the corresponding flavone derivatives with iodobenzene diacetate and trimethylsilyl halide under mild reaction conditions. The iodobenzene diacetate could be replaced by the polymer-supported iodobenzene diacetate without the decreasing activity.
引用
收藏
页码:2101 / 2106
页数:6
相关论文
共 21 条
[1]   A mild and effective iodination method using iodine in the presence of bis-(trifluoroacetoxy)iodobenzene [J].
Benhida, R ;
Blanchard, P ;
Fourrey, JL .
TETRAHEDRON LETTERS, 1998, 39 (38) :6849-6852
[2]   REGIOSPECIFIC SUBSTITUTION OF N-ACYL-2,3-DIHYDRO-4-PYRIDONES AT C-5 VIA HALOGENATION AND CROSS-COUPLING [J].
COMINS, DL ;
JOSEPH, SP ;
CHEN, XH .
TETRAHEDRON LETTERS, 1995, 36 (50) :9141-9144
[3]  
DAURIA M, 1995, TETRAHEDRON LETT, V36, P4883
[4]  
DIKE SY, 1989, SYNTHETIC COMMUN, V20, P3443
[5]   Hypervalent iodine chemistry: Mechanistic investigation of the novel haloacetoxylation, halogenation, and acetoxylation reactions of 1,4-dimethoxynaphthalenes [J].
Evans, PA ;
Brandt, TA .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (16) :5321-5326
[6]   Novel haloacetoxylation of 1,4-dimethoxynaphthalenes using hypervalent iodine chemistry [J].
Evans, PA ;
Brandt, TA .
TETRAHEDRON LETTERS, 1996, 37 (36) :6443-6446
[7]  
Evans PA, 1997, SYNLETT, P968
[8]  
FORLANI L, 1980, SYNTHESIS-STUTTGART, P487
[9]   An efficient synthesis of 2-aryl and 2-alkenyl-3-alkoxy-cyclohexenones by a modified Stille reaction [J].
Furness, MS ;
Robinson, TP ;
Goldsmith, DJ ;
Bowen, JP .
TETRAHEDRON LETTERS, 1999, 40 (03) :459-462
[10]  
GAGGAD HL, 1979, INDIAN J CHEM B, V17, P641