Luminescent palladium complexes containing thioamide-based SCS pincer ligands

被引：61

作者：

Akaiwa, M ^{[1
]}

Kanbara, T ^{[1
]}

Fukumoto, H ^{[1
]}

Yamamoto, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 18期

关键词：

palladium; pincer ligand; thioamide; luminescence;

D O I：

10.1016/j.jorganchem.2005.06.026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thioamide-based tridentate ligands, 1,3-benzenedicarbothioamides (1a-c), were used to afford pincer palladium(II) complexes (Pd(1-H)Cl, 2a-c) with eta(3)-S,C,S type coordination. The complexes exhibit strong emission in a glassy frozen state as well as in the solid state. The decay lifetime of the emission from the complexes is in a range of 8-9 x 10(-5) s, which is indicative of phosphorescent emission. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：4192 / 4196

页数：5

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