Highly ordered merocyanine dye assemblies by supramolecular polymerization and hierarchical self-organization

被引:144
作者
Würthner, F [1 ]
Yao, S
Beginn, U
机构
[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany
[2] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52056 Aachen, Germany
关键词
aggregation; dyes/pigments; polymethines; self-assembly; supramolecular polymers;
D O I
10.1002/anie.200351414
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Step by step: Bis(merocyanine) dyes 1 self-assemble in a stepwise manner with increasing concentration to afford supramolecular polymers, organogels, and liquid-crystalline phases. The close contacts between the chromophores within these superstructures enables strong D- and H-type excitonic coupling to be observed.
引用
收藏
页码:3247 / 3250
页数:4
相关论文
共 32 条
[1]   First phenylenevinylene based organogels:: Self-assembled nanostructures via cooperative hydrogen bonding and π-stacking [J].
Ajayaghosh, A ;
George, SJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) :5148-5149
[2]   Supramolecular polymers [J].
Brunsveld, L ;
Folmer, BJB ;
Meijer, EW ;
Sijbesma, RP .
CHEMICAL REVIEWS, 2001, 101 (12) :4071-4097
[3]   The thermodynamics of self-assembly [J].
Chi, XL ;
Guerin, AJ ;
Haycock, RA ;
Hunter, CA ;
Sarson, LD .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (24) :2563-2565
[4]  
Dietz F., 1973, J INFORM REC MATER, V1, P157
[5]   Self-assembly of disk-shaped molecules to coiled-coil aggregates with tunable helicity [J].
Engelkamp, H ;
Middelbeek, S ;
Nolte, RJM .
SCIENCE, 1999, 284 (5415) :785-788
[6]   Physical basis of self-assembly.: Part 2.: A theoretical and experimental study of the self-assembly of a zinc meso-pyridyl porphyrin [J].
Ercolani, G ;
Ioele, M ;
Monti, D .
NEW JOURNAL OF CHEMISTRY, 2001, 25 (06) :783-789
[7]   Physical basis of self-assembly macrocyclizations [J].
Ercolani, G .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (29) :5699-5703
[8]   AGGREGATION OF SENSITIZING DYES IN SOLUTION AND THEIR ADSORPTION ONTO SILVER-HALIDES [J].
HERZ, AH .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1977, 8 (04) :237-298
[9]   Electron-transfer dyads suitable for novel self-assembled light-harvesting antenna/electron-transfer devices [J].
Holzwarth, AR ;
Katterle, M ;
Müller, MG ;
Ma, YZ ;
Prokhorenko, V .
PURE AND APPLIED CHEMISTRY, 2001, 73 (03) :469-474
[10]  
Huber R., 1989, ANGEW CHEM, V101, P849