3D networks constructed using both coordinative and hydrogen bonding:: synthesis, structure and magnetic properties of M(tcm)2(H2O)2•Me4pyz, M = Co, Ni

被引：23

作者：

Batten, SR ^{[1
]}

Hoskins, BF

Moubaraki, B

Murray, KS

Robson, R

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3052, Australia

[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

来源：

CRYSTENGCOMM | 2001年 / 08期

关键词：

D O I：

10.1039/b009438m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-dimensional coordination polymer chains of M(tcm)(2) (H2O)(2) (M=Co, Ni; tcm=tricyanomethanide, C(CN)(3)(-), Me(4)pyz=tetramethylpyrazine) are linked into 3D networks by hydrogen bonding between the chains and the intercalated Me(4)pyz molecules, and between the chains themselves. Very weak magnetic coupling is observed for the high-spin d(7) and d(8) ions with no evidence of long-range order.

引用

页数：3

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