Self-organized heteroditopic macrocyclic superstructures

被引：106

作者：

Barboiu, M

Vaughan, G

van der Lee, A

机构：

[1] INst Europeen Membranes, CNRS, UMR 5635, F-34095 Montpellier, France

[2] European Synchrotron Radiat Facil, F-38043 Grenoble, France

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 17期

关键词：

D O I：

10.1021/ol035096r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of heteroditopic macrocyclic ureido receptors and of their NaX complexes is described. NMR studies and determination of the crystal structure show the formation of self-organized dimeric or polymeric superstructures by a cooperative macrocyclic cation complexation, anion-hydrogen bonding, and pi-pi stacking interactions. Membrane transport experiments show a direct relation between the synergetic ion-pair recognition and the transport properties of these molecular information transfer devices.

引用

页码：3073 / 3076

页数：4

共 18 条

[1] AKIAMA M, 1994, SPECTROCHIM ACTA A, V50, P317
[2] Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[3] 2-G
[4] Bong DT, 2001, ANGEW CHEM INT EDIT, V40, P988, DOI 10.1002/1521-3773(20010316)40:6<988::AID-ANIE9880>3.0.CO
[5] 2-N
[6] Characterization of hydrogen-bonded aggregates in chloroform by electrospray ionization mass spectrometry
Cheng, XH
Gao, QY
Smith, RD
Simanek, EE
Mammen, M
Whitesides, GM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (06) : 2204 - 2206
[7] de Loos M, 2001, ANGEW CHEM INT EDIT, V40, P613, DOI 10.1002/1521-3773(20010202)40:3<613::AID-ANIE613>3.0.CO
[8] 2-K
[9] ENCODING AND DECODING HYDROGEN-BOND PATTERNS OF ORGANIC-COMPOUNDS
ETTER, MC
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) : 120 - 126
[10] Synthetic models of cation-conducting channels
Gokel, GW
Mukhopadhyay, A
[J]. CHEMICAL SOCIETY REVIEWS, 2001, 30 (05) : 274 - 286

← 1 2 →