Kinetic study of the interconversion of the regio-isomeric iron tricarbonyl complexes derived from 4-bromotropone

被引：6

作者：

Banwell, MG

Schuhbauer, HM

机构：

[1] Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 19期

关键词：

D O I：

10.1021/om960294q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complexes, 1 and 2, have been prepared and their interconversion has been studied by H-1 NMR spectroscopy; the activation enthalpies and entropies as well as the equilibrium constants for these reversible intramolecular first-order processes have been determined, The iron tricarbonyl complex 3 of 3-bromotropone has also been prepared, but this does not isomerize to regio-isomer 4.

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页码：4078 / 4080

页数：3

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