Gadolinium silicate gate dielectric films with sub-1.5 nm equivalent oxide thickness

被引:85
作者
Gupta, JA [1 ]
Landheer, D [1 ]
McCaffrey, JP [1 ]
Sproule, GI [1 ]
机构
[1] Natl Res Council Canada, Inst Microstruct Sci, Ottawa, ON K1A 0R6, Canada
关键词
D O I
10.1063/1.1356725
中图分类号
O59 [应用物理学];
学科分类号
摘要
GdSi(x)O(y) gate dielectric films were deposited on Si(001) substrates using ultra-high-vacuum electron-beam evaporation from pressed-powder targets. Transmission electron microscopy showed that the films were amorphous as deposited and remained amorphous when annealed to temperatures up to 900 degreesC. Capacitance-voltage measurements indicate an equivalent oxide thickness (EOT) of 13.4 Angstrom for a film with composition GdSi(0.56)O(2.59) determined by in situ x-ray photoelectron emission spectroscopy. After forming gas annealing at 500 degreesC the EOT was reduced to 11.0 Angstrom, at a physical thickness of 45 Angstrom. The same film has a low leakage current of approximately 5.7 x 10(-3) Angstrom cm(-2) at +1 V, a reduction of 8.7 x 10(4) compared to current density estimates of SiO(2) films with the same specific capacitance. (C) 2001 American Institute of Physics.
引用
收藏
页码:1718 / 1720
页数:3
相关论文
共 18 条
[1]   Direct extraction of the electron tunneling effective mass in ultrathin SiO2 [J].
Brar, B ;
Wilk, GD ;
Seabaugh, AC .
APPLIED PHYSICS LETTERS, 1996, 69 (18) :2728-2730
[2]   Yttrium silicate formation on silicon: Effect of silicon preoxidation and nitridation on interface reaction kinetics [J].
Chambers, JJ ;
Parsons, GN .
APPLIED PHYSICS LETTERS, 2000, 77 (15) :2385-2387
[3]  
Felsche J., 1973, STRUCT BOND, V13, P99, DOI DOI 10.1007/3-540-06125-8_3
[4]   Atomic beam deposition of lanthanum- and yttrium-based oxide thin films for gate dielectrics [J].
Guha, S ;
Cartier, E ;
Gribelyuk, MA ;
Bojarczuk, NA ;
Copel, MC .
APPLIED PHYSICS LETTERS, 2000, 77 (17) :2710-2712
[5]   Interfacial layer formation in Gd2O3 films deposited directly on Si(001) [J].
Gupta, JA ;
Landheer, D ;
Sproule, GI ;
McCaffrey, JP ;
Graham, MJ ;
Yang, KC ;
Lu, ZH ;
Lennard, WN .
APPLIED SURFACE SCIENCE, 2001, 173 (3-4) :318-326
[6]  
Hauser JR, 1998, AIP CONF PROC, V449, P235
[7]   Thermodynamic stability of binary oxides in contact with silicon [J].
Hubbard, KJ ;
Schlom, DG .
JOURNAL OF MATERIALS RESEARCH, 1996, 11 (11) :2757-2776
[8]   Electron spectroscopic analysis of the SiO2/Si system and correlation with metal-oxide-semiconductor device characteristics [J].
Iwata, S ;
Ishizaka, A .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (09) :6653-6713
[9]   High ε gate dielectrics Gd2O3 and Y2O3 for silicon [J].
Kwo, J ;
Hong, M ;
Kortan, AR ;
Queeney, KT ;
Chabal, YJ ;
Mannaerts, JP ;
Boone, T ;
Krajewski, JJ ;
Sergent, AM ;
Rosamilia, JM .
APPLIED PHYSICS LETTERS, 2000, 77 (01) :130-132
[10]   Multiplet structure in high-resolution and spin-resolved x-ray photoemission from gadolinium [J].
Lademan, WJ ;
See, AK ;
Klebanoff, LE ;
vanderLaan, G .
PHYSICAL REVIEW B, 1996, 54 (23) :17191-17198