(Diethylenetriamine)bis(isothiocyanato)zinc(II)

被引:5
作者
Lu, TH [1 ]
Lo, JM
Chen, BH
Yeh, MY
Tung, SF
Huang, WT
Yao, HH
机构
[1] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan
[2] Natl Tsing Hua Univ, Dept Nucl Sci, Hsinchu 300, Taiwan
[3] Natl Cheng Kung Univ, Dept Chem, Tainan 701, Taiwan
[4] Natl Cheng Kung Univ, So Instrument Ctr, Tainan 701, Taiwan
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷
关键词
D O I
10.1107/S0108270198002753
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the X-ray crystal structure of the title complex, [N-(2-aminoethyl)-1,2-ethanediamine-kappa(3)N]bis(isothiocyanato-N)zinc(II), [Zn(NCS)(2)(C4H13N3)], the Zn-II ion and the two isothiocyanate groups lie on a mirror plane and the diethylenetriamine ligand is disordered. The Zn-II ion is coordinated to the three N atoms of the diethylenetriamine ligand and to the N atoms of two isothiocyanate ions. The primary coordination sphere about the Zn-II ion can be regarded as a symmetric trigonal bipyramid. The ordered Zn-N distances range from 1.984(7) to 2.252 (8) Angstrom.
引用
收藏
页码:1067 / 1068
页数:2
相关论文
共 16 条
[1]   AMBIDENTATE LIGANDS, THE SCHIZOPHRENICS OF COORDINATION CHEMISTRY [J].
BURMEISTER, JL .
COORDINATION CHEMISTRY REVIEWS, 1990, 105 :77-133
[2]  
*ENR, 1989, CAD 4 SOFTW VERS 5 0
[3]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[4]   NRCVAX - AN INTERACTIVE PROGRAM SYSTEM FOR STRUCTURE-ANALYSIS [J].
GABE, EJ ;
LEPAGE, Y ;
CHARLAND, JP ;
LEE, FL ;
WHITE, PS .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1989, 22 :384-387
[5]   NITRITO-NITRO LINKAGE ISOMERIZATION IN THE SOLID-STATE .1. X-RAY CRYSTALLOGRAPHIC STUDIES OF TRANS-BIS(ETHYLENEDIAMINE)(ISOTHIOCYANATO)NITRITOCOBOLT(III) AND TRANS-BIS(ETHYLENEDIAMINE)(ISOTHIOCYANATO)NITROCOBALT(III) PERCHLORATE AND IODIDE [J].
GRENTHE, I ;
NORDIN, E .
INORGANIC CHEMISTRY, 1979, 18 (04) :1109-1116
[6]  
Johnson C. K., 1976, ORNL5138
[7]   A VERSATILE MACROCYCLIC [12]ANEN3 FOR INTERCONVERSION OF TETRAHEDRAL AND TRIGONAL BIPYRAMIDAL ZINC(II) COMPLEXES - RELEVANCE TO 4-COORDINATE REVERSIBLE-ARROW 5-COORDINATE GEOMETRIES OF ZINC(II) IN CARBONIC-ANHYDRASE [J].
KIMURA, E ;
KOIKE, T ;
SHIONOYA, M ;
SHIRO, M .
CHEMISTRY LETTERS, 1992, (05) :787-790
[8]   CRYSTAL AND MOLECULAR-STRUCTURE OF A LATTICE ADDUCT, HGPH2.2[HG(SCN)2(PPH3)2] - AN UNUSUAL CASE OF 2-CO-ORDINATE AND 4-CO-ORDINATE MERCURY IN THE SAME UNIT-CELL [J].
LOBANA, TS ;
SANDHU, MK ;
POVEY, DC ;
SMITH, GW ;
RAMDAS, V .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (11) :2339-2341
[9]   THIOCYANATOBIS(TRIPHENYLPHOSPHINE)GOLD(I) [J].
MUIR, JA ;
MUIR, MM ;
ARIAS, S .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (APR) :1318-1320
[10]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&