Oxidative dearomatization of phenols and anilines via λ3- and λ5-ilodane-mediated phenylation and oxygenation

被引：49

作者：

Quideau, S

Pouységu, L

Ozanne, A

Gagnepain, J

机构：

[1] Inst Europeen Chim & Biol, F-33607 Pessac, France

[2] Univ Bordeaux 1, Lab Chim Substances Vegetales, Ctr Rech & Chim Mol, F-33405 Talence, France

来源：

MOLECULES | 2005年 / 10卷 / 01期

关键词：

iodanes; phenols; anilines; dearomatization; cyclohexadienones; orthoquinol imines;

D O I：

10.3390/10010201

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Treatment of 2-methylphenols with chloro(diphenyl)lambda(3)-iodane led to their regioselective dearomatizing 2-phenylation into cyclohexa-2,4-dienone derivatives via a proposed ligand coupling reaction. In the same vein of investigation, treatment of 2-methylanilines with the lambda(5)-iodane 2-iodoxybenzoic acid IBX reagent led to their regioselective dearomatization into previously undescribed ortho-quinol imines.

引用

页码：201 / 216

页数：16

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