Tunable, strongly-donating perylene photosensitizers for dye-sensitized solar cells

被引：72

作者：

Mathew, Simon ^{[1
,2
]}

Imahori, Hiroshi ^{[1
,2
,3
]}

机构：

[1] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Nishikyo Ku, Kyoto 6158510, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kyoto Univ, Fukui Inst Fundamental Chem, Sakyo Ku, Kyoto 6068103, Japan

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2011年 / 21卷 / 20期

关键词：

ELECTRON-TRANSFER; TIO2; FILMS; EFFICIENCY; FEATURES;

D O I：

10.1039/c1jm10993f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Broadly absorbing perylene dyes bearing three-triarylamine groups were synthesized via Sonogashira coupling. The triarylamine moieties allowed further installation of electron donating ability, to enable tuning of the oxidation potential and optical band gap. With introducing more electron-donating groups into the three-triarylamine moieties the device performance was improved. The trend can be rationalized by the distribution of the electron density in the HOMO of the perylene moiety as well as the light-harvesting property of the perylene dyes.

引用

页码：7166 / 7174

页数：9

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