Helical polymer brushes with a preferred-handed helix-sense triggered by a terminal optically active group in the pendant

被引：54

作者：

Maeda, Katsuhiro ^{[1
]}

Wakasone, Shiho ^{[1
]}

Shimomura, Kouhei ^{[1
]}

Ikai, Tomoyuki ^{[1
]}

Kanoh, Shigeyoshi ^{[1
]}

机构：

[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Kanazawa, Ishikawa 9201192, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 27期

基金：

日本学术振兴会;

关键词：

POLY(PHENYLACETYLENE) DERIVATIVES BEARING; MACROMOLECULAR HELICITY; HIERARCHICAL AMPLIFICATION; ASYMMETRIC POLYMERIZATION; CHIRAL SUBSTITUENTS; ANIONIC INITIATORS; BULKY SUBSTITUENT; LIQUID-CRYSTAL; SCREW SENSE; END-GROUP;

D O I：

10.1039/c2cc00024e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Helical polymer brushes with a preferred-handed helix-sense composed of a poly(phenylacetylene) backbone and poly(phenyl isocyanate) pendants are synthesized. The helix-sense of the backbone is effectively controlled by the helical chirality of the pendants, which is triggered by an optically active group introduced at the pendant terminal.

引用

页码：3342 / 3344

页数：3

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