Macroscopically ordered polymer/CaCO3 hybrids prepared by using a liquid-crystalline template

被引：80

作者：

Nishimura, Tatsuya ^{[1
]}

Ito, Takahiro ^{[1
]}

Yamamoto, Yuya ^{[1
]}

Yoshio, Masafumi ^{[1
]}

Kato, Takashi ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 15期

关键词：

bioinorganic chemistry; crystal growth; liquid crystals; organic-inorganic hybrid composites; template synthesis;

D O I：

10.1002/anie.200705062

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Unidirectionally aligned hybrids consisting of chitin and calcite were obtained by template crystallization of CaCO3 in an ordered chitin film with nematic liquid-crystalline molecular alignment. The picture shows the resulting chitin matrix containing CaCO3 rods, schematically and in the form of an optical micrograph, and the selected-area electron diffraction pattern of a thin section of a single rod. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2800 / 2803

页数：4

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