Flavin-catalyzed generation of diimide: An environmentally friendly method for the aerobic hydrogenation of olefins

被引：99

作者：

Imada, Y ^{[1
]}

Iida, H ^{[1
]}

Naota, T ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 42期

关键词：

D O I：

10.1021/ja053976q

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first green and practical method for aerobic hydrogenation" involving the use of hydrazine and an organocatalyst is described. Olefins can be hydrogenated by treatment with hydrazine in the presence of a 5-ethyl-3-methyllumiflavinium perchlorate (FlEt+·ClO4-) catalyst under O2 atmosphere to give the corresponding hydrogenated products in excellent yields along with environmentally benign water and molecular nitrogen as the only waste products. Copyright © 2005 American Chemical Society."

引用

页码：14544 / 14545

页数：2

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