Electrochromism of titanate-based nanotubes

被引：142

作者：

Tokudome, H ^{[1
]}

Miyauchi, M ^{[1
]}

机构：

[1] TOTO Ltd, Res Inst, Chigasaki, Kanagawa 2538577, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 13期

关键词：

electrochromism; layered compounds; nanotubes; thin films; titanium;

D O I：

10.1002/anie.200462448

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A transparent thin film of titanate nanotubes turns brown under cathodic polarization in water. This electrochromism arises from the creation of Ti3+ centers by proton intercalation into the interlayer separation of nanotubes. The significant color change of the titanate nanotubes is a consequence of their layered nanostructure. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1974 / 1977

页数：4

共 19 条

[1]

Chen Q, 2002, ADV MATER, V14, P1208, DOI 10.1002/1521-4095(20020903)14:17<1208::AID-ADMA1208>3.0.CO

[2]

2-0

[3] The structure of trititanate nanotubes [J].

Chen, Q ;

Du, GH ;

Zhang, S ;

Peng, LM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 :587-593

[4] INFRARED ABSORPTION OF REDUCED RUTILE TIO2 SINGLE CRYSTALS [J].

CRONEMEYER, DC .

PHYSICAL REVIEW, 1959, 113 (05) :1222-1226

[5] Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].

Decher, G .

SCIENCE, 1997, 277 (5330) :1232-1237

[6] Single-crystal gallium nitride nanotubes [J].

Goldberger, J ;

He, RR ;

Zhang, YF ;

Lee, SW ;

Yan, HQ ;

Choi, HJ ;

Yang, PD .

NATURE, 2003, 422 (6932) :599-602

[7]

Granqvist C. G., 1995, HDB INORGANIC ELECTR

[8] Formation of titanium oxide nanotube [J].

Kasuga, T ;

Hiramatsu, M ;

Hoson, A ;

Sekino, T ;

Niihara, K .

LANGMUIR, 1998, 14 (12) :3160-3163

[9] Quasi-aligned single-crystalline W18O49 nanotubes and nanowires [J].

Li, YB ;

Bando, Y ;

Golberg, D .

ADVANCED MATERIALS, 2003, 15 (15) :1294-+

[10] ASSEMBLY OF MULTICOMPONENT PROTEIN FILMS BY MEANS OF ELECTROSTATIC LAYER-BY-LAYER ADSORPTION [J].

LVOV, Y ;

ARIGA, K ;

ICHINOSE, I ;

KUNITAKE, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (22) :6117-6123

← 1 2 →