Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule

被引：38

作者：

Kulasekharan, Revathy ^{[1
]}

Choudhury, Rajib ^{[1
]}

Prabhakar, Rajeev ^{[1
]}

Ramamurthy, V. ^{[1
]}

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33124 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

基金：

美国国家科学基金会;

关键词：

CONFORMATIONAL CONTROL; EXCITED-STATE; PROTEINS; BEHAVIOR; CLEAVAGE;

D O I：

10.1039/c0cc05337f

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones.

引用

页码：2841 / 2843

页数：3

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