Transition from disc to rod-like shape of 16-3-16 dimeric micelles in aqueous solutions

被引：28

作者：

Aswal, VK ^{[1
]}

De, S

Goyal, PS

Bhattacharya, S

Heenan, RK

机构：

[1] Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India

[2] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

[3] Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1998年 / 94卷 / 19期

关键词：

D O I：

10.1039/a805307c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Small-angle neutron scattering (SANS) measurements from bis-cationic C16H33N+(CH3)(2)-(CH2)(3)-N+ (CH3)(2)C16H33 2Br(-) dimeric surfactant, referred to as 16-3-16, at different concentrations and temperatures, are reported. It is seen that micelles are disc-like for concentrations C = 2.5 and 10 mM at temperature T = 30 degrees C. At low concentration C = 0.5 mM micelles are rod-like. Similarly, there is a disc to rod-like transition of micelles on increasing the temperature. For C = 2.5 mM, micelles are rod-like at T = 45 and 70 degrees C.

引用

页码：2965 / 2967

页数：3

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