A C3-symmetric chiral hexadentate podand ligand based on a tris(pyrazolyl)borate core

被引:31
作者
Motson, GR
Mamula, O
Jeffery, JC
McCleverty, JA
Ward, MD
von Zelewsky, A
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ Fribourg, Inst Inorgan Chem, CH-1700 Fribourg, Switzerland
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / Royal Society of Chemistry卷 / 09期
关键词
D O I
10.1039/b102295b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A hexadentate podand ligand having C-3 symmetry has been prepared, consisting of a tris(pyrazolyl)borate core bearing pinene-functionalised 2-pyridyl units attached to the C-3 position of each pyrazolyl ring such that each arm is a chiral bidentate chelate; complexes with Tl(I) and Tb(III) have been prepared and structurally characterised.
引用
收藏
页码:1389 / 1391
页数:3
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