Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges

被引:1195
作者
Du, Pingwu [1 ]
Eisenberg, Richard [1 ]
机构
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
关键词
ELECTROCATALYTIC HYDROGEN EVOLUTION; OXYGEN-EVOLVING CATALYST; VISIBLE-LIGHT; CRYSTAL-STRUCTURE; SOLAR-ENERGY; ACTIVE-SITE; MOLECULAR CATALYSTS; HOMOGENEOUS SYSTEM; IRON HYDROGENASE; CARBON-DIOXIDE;
D O I
10.1039/c2ee03250c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article reviews recent significant advances in the field of water splitting. Catalysts play very important roles in two half reactions of water splitting - water reduction and water oxidation. Considering potential future applications, catalysts made of cheap and earth abundant element(s) are especially important for economically viable energy conversion. This article focuses only on catalysts made of cobalt (Co), nickel (Ni) and iron (Fe) elements for water reduction and water oxidation. Different series of catalysts that can be applied in electrocatalytic and photocatalytic water spitting are discussed in detail and their catalytic mechanisms are introduced. Finally, the future outlook and perspective of catalysts made of earth abundant elements will be discussed.
引用
收藏
页码:6012 / 6021
页数:10
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