[Zn(bim)2] • (H2O)1.67:: A metalorganic open-framework with sodalite topology

被引：149

作者：

Huang, XC

Zhang, JP

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Shantou Univ, Dept Chem, Shantou 515063, Peoples R China

来源：

CHINESE SCIENCE BULLETIN | 2003年 / 48卷 / 15期

基金：

中国国家自然科学基金;

关键词：

zinc(II); benzimidazolate; sodalite;

D O I：

10.1360/03wb0079

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The new coordination polymer formulated as [Zn(bim)(2)](H2O)(1.67) (Hbim = benzimidazole, bim = benzimidazolate) has been synthesized and shown by single-crystal structural analysis to be a three-dimensional network with the 4 2 6 4 sodalite topology, constructed by tetrahedral building blocks, [Zn(biM)(4)](2-). Each sodalite cage defined by the 24 zinc atoms at the apexes centers hosts 10 water molecules (ca. 18% occupancy).

引用

页码：1531 / 1534

页数：4

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