Controlled polymerization of 2-hydroxyethyl methacrylate by ATRP at ambient temperature

被引：283

作者：

Robinson, KL ^{[1
]}

Khan, MA ^{[1
]}

Báñez, MVD ^{[1
]}

Wang, XS ^{[1
]}

Armes, SP ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

MACROMOLECULES | 2001年 / 34卷 / 10期

关键词：

D O I：

10.1021/ma0019611

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The efficient, controlled polymerization of 2-hydroxyethyl methacrylate (HEMA) is achieved using atom transfer radical polymerization in methanol/water mixtures or pure methanol at 20 degreesC. The evolution of molecular weight with conversion is linear; polydispersities are around 1.1 for polymerization in methanol and around 1.2-1.3 for syntheses in 50:50 methanol/water mixtures, indicating good living character.

引用

页码：3155 / 3158

页数：4

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