Thermoresponsive fluorescent polymers based on a quaterthiophene-containing boron dipyrromethene (Bodipy) dyad dispersed in silicone rubber

被引:17
作者
Benniston, Andrew C. [1 ]
Copley, Graeme [1 ]
Harriman, Anthony [1 ]
Ryan, Ruth [1 ]
机构
[1] Newcastle Univ, Mol Photon Lab, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
基金
英国工程与自然科学研究理事会;
关键词
TEMPERATURE; BIS(BENZOXAZOLYL)STILBENE; DEFORMATION; DERIVATIVES; POTENTIALS; CONVERSION; FILMS;
D O I
10.1039/c0jm03351k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A quaterthiophene-based boron dipyrromethene (Bodipy) dyad when dispersed uniformally in silicone rubber produces a thermoresponsive fluorescent material. The yellow fluorescence colour observed at low temperatures <200 degrees C changes to green upon heating the polymer. In contrast, the phenylene-based Bodipy dyad in silicone rubber displays a partial on to off fluorescence change at around 70 degrees C.
引用
收藏
页码:2601 / 2608
页数:8
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