Crossover parametric equation of state for Ising-like systems

被引:73
作者
Agayan, VA [1 ]
Anisimov, MA
Sengers, JV
机构
[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
[2] Univ Maryland, Dept Chem Engn, College Pk, MD 20742 USA
关键词
D O I
10.1103/PhysRevE.64.026125
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We present a parametric equation for the thermodynamic properties in the critical region of three-dimensional Ising-like systems which include fluids and fluid mixtures. The equation of state incorporates a crossover from singular Ising behavior asymptotically close to the critical point to classical (mean-field) behavior further away from the critical point, characterized by two physical crossover parameters: a coupling constant related to the strength and range of molecular interactions and a "cutoff" wave number for the critical fluctuations. In the asymptotic Ising limit, the crossover equation reproduces the most recent theoretical estimates for the universal ratios of the leading and correction-to-scaling critical amplitudes. The equation has been tested by comparing it with recent experimental thermodynamic-property data for He-3 near its vapor-liquid critical point.
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页数:19
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