Ion exchange membrane based on block copolymers. Part III: preparation of cation exchange membrane

被引:83
作者
Hwang, GJ
Ohya, H
Nagai, T
机构
[1] Yokohama Natl Univ, Dept Mat Sci & Chem Engn, Yokohama, Kanagawa 2408501, Japan
[2] Japan Atom Energy Res Inst, Oarai, Ibaraki 3191195, Japan
关键词
polysulfone; block copolymers; ion exchange membrane; ion exchange capacity; cation selective membrane;
D O I
10.1016/S0376-7388(98)00331-7
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new type of ion exchange membrane was investigated for the purpose of applying electrodialysis process. The cation exchange membrane was prepared by sulfonation of the home-made block copolymers of polysulfone (PSf) and polyphenylenesulfidesulfone (PPSS). The lowest measured membrane area resistance, equilibrated in 2 M (mol/dm(3)) KCI aqueous solution, was 2.5 Omega cm(2). The cation exchange capacity reached up to 1.9 meq/(g-dry-resin), and the transport number of K+ was in the 0.77-0.87 range. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:61 / 65
页数:5
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