Selenium-catalyzed oxidations with aqueous hydrogen peroxide. 2. Baeyer-Villiger reactions in homogeneous solution

被引：139

作者：

ten Brink, GJ ^{[1
]}

Vis, JM ^{[1
]}

Arends, IWCE ^{[1
]}

Sheldon, RA ^{[1
]}

机构：

[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 66卷 / 07期

关键词：

D O I：

10.1021/jo0057710

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several diselenides were tested for catalytic activity in Baeyer-Villiger reactions with 60% aqueous hydrogen peroxide. Bis [3,5-bis(trifluoromethyl)phenyl] diselenide forms the corresponding 3,5-bis(trifluoromethyl)benzene seleninic acid in situ, which is a highly reactive and selective catalyst for the oxidation of carbonyl compounds in 1,1,1,3,3,3-hexafluoro-2-propanol, 2,2,2-trifluoroethanol,, or dichloromethane.

引用

页码：2429 / 2433

页数：5

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