Efficient and highly selective iron-catalyzed reduction of nitroarenes

被引：198

作者：

Jagadeesh, Rajenahally V. ^{[1
]}

Wienhoefer, Gerrit ^{[1
]}

Westerhaus, Felix A. ^{[1
]}

Surkus, Annette-Enrica ^{[1
]}

Pohl, Marga-Martina ^{[1
]}

Junge, Henrik ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst fu r Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 39期

关键词：

AROMATIC NITRO-COMPOUNDS; OXIDE HYDROXIDE CATALYST; HYDRAZINE HYDRATE; CHEMOSELECTIVE HYDROGENATION; AMINES; NITROAROMATICS; NANOPARTICLES; CONVENIENT; KETONES; AMIDES;

D O I：

10.1039/c1cc13728j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyrolysis of iron-phenanthroline complexes supported on carbon leads to highly selective catalysts for the reduction of structurally diverse nitroarenes to anilines in 90-99% yields. Excellent chemoselectivity for the nitro group reduction is demonstrated.

引用

页码：10972 / 10974

页数：3

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