Solvothermal synthesis and crystal structure of [La(ethylenediamine)4Cl]In2Te4:: A 1-D indium telluride

被引：35

作者：

Chen, Z

Li, J ^{[1
]}

Chen, F

Proserpio, DM

机构：

[1] Rutgers State Univ, Dept Chem, Camden, NJ 08102 USA

[2] Rider Univ, Dept Chem, Lawrenceville, NJ 08648 USA

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

来源：

INORGANICA CHIMICA ACTA | 1998年 / 273卷 / 1-2期

关键词：

tellurides; solvothermal reactions; crystal structures;

D O I：

10.1016/S0020-1693(97)06145-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystal growth of metal tellurides and tellurometalates employing solvothermal reactions at temperatures below 200 degrees C have resulted in [La(ethylenediamine)(4)Cl]In2Te4 (1). Single crystal X-ray diffraction analyses show that 1 belongs to the tetragonal crystal system, space group I4 (No. 79) a=13.471(3), c=7.295(3) Angstrom, Z=2.1 is a Zintl compound containing one-dimensional polymeric chains of [GRAPHICS] built of InTe4 tetrahedra sharing opposite edges, and [La(en)(4)Cl](2+) (ethylenediamine=en) cations with regular monocapped square-antiprism nona-coordination. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：255 / 258

页数：4

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