Coordination assemblies from a Pd(II)-cornered square complex

被引:1643
作者
Fujita, M [1 ]
Tominaga, M [1 ]
Hori, A [1 ]
Therrien, B [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
关键词
D O I
10.1021/ar040153h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The [enPd(II)](2+) (en = ethylenediamine) unit has emerged as a versatile building block in molecular self-assembly. In particular, the 90 degrees coordination angle of the metal has been judiciously used in the design of new discrete two- and three-dimensional structures. Our last 15 years of work with the Pd(II)-cornered unit is summarized in this Account, from the spontaneous formation of a Pd-4 square metal complex to a family of architectures such as cages, bowls, boxes, tubes, catenanes, and spheres.
引用
收藏
页码:369 / 378
页数:10
相关论文
共 53 条
[1]   Quantitative formation of coordination nanotubes templated by rodlike guests [J].
Aoyagi, M ;
Biradha, K ;
Fujita, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (32) :7457-7458
[2]   Spectroscopic and crystallographic studies on the stability of self-assembled coordination nanotubes [J].
Aoyagi, M ;
Tashiro, S ;
Tominaga, M ;
Biradha, K ;
Fujita, M .
CHEMICAL COMMUNICATIONS, 2002, (18) :2036-2037
[3]   ISOSTRUCTURAL, ALTERNATELY-CHARGED RECEPTOR STACKS - THE INCLUSION COMPLEXES OF HYDROQUINONE AND CATECHOL DIMETHYL ETHERS WITH CYCLOBIS(PARAQUAT-PARA-PHENYLENE) [J].
ASHTON, PR ;
ODELL, B ;
REDDINGTON, MV ;
SLAWIN, AMZ ;
STODDART, JF ;
WILLIAMS, DJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (11) :1550-1553
[4]   Symmetry-based metal complex cluster formation [J].
Beissel, T ;
Powers, RE ;
Raymond, KN .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (10) :1084-1086
[5]   Thin-film molecular materials based on tetrametallic "squares":: Nanoscale porosity and size-selective guest transport characteristics [J].
Bélanger, S ;
Hupp, JT ;
Stern, CL ;
Slone, RV ;
Watson, DF ;
Carrell, TG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (03) :557-563
[6]   The supposed isomerism among the pallado-diammines. [J].
Drew, HDK ;
Pinkard, FW ;
Preston, GH ;
Wardlaw, W .
JOURNAL OF THE CHEMICAL SOCIETY, 1932, :1895-1909
[7]   SPECTROSCOPIC OBSERVATION OF SELF-ASSEMBLY OF A MACROCYCLIC TETRANUCLEAR COMPLEX COMPOSED OF PT2+ AND 4,4'-BIPYRIDINE [J].
FUJITA, M ;
YAZAKI, J ;
OGURA, K .
CHEMISTRY LETTERS, 1991, (06) :1031-1032
[8]   MACROCYCLIC POLYNUCLEAR COMPLEXES [(EN)M(4,4'-BPY)]4(NO3)8 (M = PD OR PT) AS INORGANIC CYCLOPHANE - THEIR ABILITY FOR MOLECULAR RECOGNITION [J].
FUJITA, M ;
YAZAKI, J ;
OGURA, K .
TETRAHEDRON LETTERS, 1991, 32 (40) :5589-5592
[9]   Metal-directed self-assembly of two- and three-dimensional synthetic receptors [J].
Fujita, M .
CHEMICAL SOCIETY REVIEWS, 1998, 27 (06) :417-425
[10]   PREPARATION OF A MACROCYCLIC POLYNUCLEAR COMPLEX, [(EN)PD(4,4'-BPY)]4(NO3)8, WHICH RECOGNIZES AN ORGANIC-MOLECULE IN AQUEOUS-MEDIA [J].
FUJITA, M ;
YAZAKI, J ;
OGURA, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5645-5647