Long Chain Dicationic Phase Transfer Catalysts in the Condensation Reactions of Aromatic Aldehydes in Water Under Ultrasonic Effect

被引:11
作者
Esen, Ilker [1 ]
Yolacan, Cigdem [1 ]
Aydogan, Feray [1 ]
机构
[1] Yildiz Tech Univ, Dept Chem, TR-34010 Istanbul, Turkey
关键词
Phase transfer catalyst; Ultrasound-assisted synthesis; Aromatic aldehyde; Arylacrylonitrile; alpha; beta-Unsaturated ketone; CATIONIC SURFACTANTS; PHENYLACETONITRILE; CYCLOALKYLATION; OPTIMIZATION; GEMINI;
D O I
10.5012/bkcs.2010.31.8.2289
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Long chain dicationic ammonium salts were used successfully as phase transfer catalyst in the condensation reactions of aromatic aldehydes in water under ultrasonic irradiation for the first time. The quaternary salt having longer distance between the cation centers was more effective than the mono- and dicationic ones having short chain.
引用
收藏
页码:2289 / 2292
页数:4
相关论文
共 23 条
[1]
An improved synthesis of Biginelli-type compounds via phase-transfer catalysis [J].
Ahmed, Bahar ;
Khan, Riaz A. ;
Habibullah ;
Keshari, Manoj .
TETRAHEDRON LETTERS, 2009, 50 (24) :2889-2892
[2]
Cycloalkylation reactions of fatty amines with α,ω-dihaloalkanes:: Role of bis-quaternary ammonium salts as phase-transfer catalysts [J].
Ali, Hanan El-Sharkawy .
CATALYSIS COMMUNICATIONS, 2007, 8 (06) :855-860
[3]
Anastas P., 1998, GREEN CHEM THEORY PR
[4]
Interactions of gemini cationic surfactants with anionic azo dyes and their inhibited effects on dyeability of cotton fabric [J].
Bagha, Ali R. Tehrani ;
Bahrami, Hajir ;
Movassagh, Barahman ;
Arami, Mokhtar ;
Menger, Fredric M. .
DYES AND PIGMENTS, 2007, 72 (03) :331-338
[5]
Aggregation of dicationic surfactants with methyl orange in aqueous solution [J].
Buwalda, RT ;
Engberts, JBFN .
LANGMUIR, 2001, 17 (04) :1054-1059
[6]
Convenient preparation of highly active phase-transfer catalyst for catalytic asymmetric synthesis of α-alkyl- and α,α-dialkyl-α-amino acids:: application to the short asymmetric synthesis of BIRT-377 [J].
Han, ZF ;
Yamaguchi, Y ;
Kitamura, M ;
Maruoka, K .
TETRAHEDRON LETTERS, 2005, 46 (49) :8555-8558
[7]
Phase transfer catalyzed intramolecular cycloalkylation of phenylacetonitrile with α,ω-dibromoalkanes in supercritical ethane [J].
Jayachandran, JP ;
Wheeler, C ;
Eason, BC ;
Liotta, CL ;
Eckert, CA .
JOURNAL OF SUPERCRITICAL FLUIDS, 2003, 27 (02) :179-186
[8]
Jones R.A., 2001, QUATERNARY AMMONIUM
[9]
Adsorption of gemini and conventional cationic surfactants onto montmorillonite and the removal of some pollutants by the clay [J].
Li, F ;
Rosen, MJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 224 (02) :265-271
[10]
Solvent-free condensation of phenylacetonitrile and nonanenitrile with 4-methoxybenzaldehyde: optimization and mechanistic studies [J].
Loupy, A ;
Pellet, M ;
Petit, A ;
Vo-Thanh, G .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (08) :1534-1540