Chiral 2,6-lutidinyl-biscarbene complexes of palladium

被引：186

作者：

Tulloch, AAD

Danopoulos, AA ^{[1
]}

Tizzard, GJ

Coles, SJ

Hursthouse, MB

Hay-Motherwell, RS

Motherwell, WB

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

[2] UCL, Christopher Ingold Labs, London WC1H 0AJ, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 14期

关键词：

D O I：

10.1039/b103330c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral complexes of palladium, 1, with the new tridentate `pincer' ligand 2,6-lutidinyl-biscarbene (C<^>N<^>C), have been prepared; in the solid state they exhibit helical C-2 symmetrical structures which are persistent in solution at least up to 80 degreesC; the chiral nature of 1 has been established by NMR methods using Pirkle's acid as a chiral discriminating agent; racemic mixtures of 1 are highly active catalysts in Heck coupling reactions.

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页码：1270 / 1271

页数：2

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