Stereoselective sulfoxidation of α-mannopyranosyl thioglycosides:: The exo-anomeric effect in action

被引：44

作者：

Crich, D

Mataka, J

Sun, SX

Lam, KC

Rheingold, AL

Wink, DJ

机构：

[1] Univ Illinois, Dept Chem, Chicago, IL 60607 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a804126a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

As a consequence of the exo-anomeric effect, and in contrast to their beta-anomers, alpha-thioglycosides undergo stereoselective oxidation to give very predominantly the R-sulfoxides, as revealed by X-ray crystallography.

引用

页码：2763 / 2764

页数：2

共 16 条

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