Acetylenic dithiafulvene derived donor-π-acceptor dyads:: synthesis, electrochemistry and non-linear optical properties

被引:20
作者
Nielsen, MB [1 ]
Petersen, JC
Thorup, N
Jessing, M
Andersson, AS
Jepsen, AS
Gisselbrecht, JP
Boudon, C
Gross, M
机构
[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
[2] Danish Inst Fundamental Metrol, DK-2800 Lyngby, Denmark
[3] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark
[4] Univ So Denmark, Dept Chem, DK-5230 Odense, Denmark
[5] Univ Louis Pasteur Strasbourg 1, CNRS, Lab Electrochim & Chim Phys Corps Solide, UMR 7512, F-67000 Strasbourg, France
关键词
D O I
10.1039/b504124d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A selection of donor-acceptor chromophores containing the redox-active dithiafulvene unit about acetylenic and aryl scaffolds has been synthesised. The molecules were studied for their optical, redox and structural properties. Moreover, third-order non-linear optical properties were investigated as a function of molecular structure.
引用
收藏
页码:2599 / 2605
页数:7
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