Bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato]copper(II)}cadmium(II) dioxane solvate

被引：22

作者：

Ercan, F ^{[1
]}

Ülkü, D

Atakol, O

Dinçer, FN

机构：

[1] Hacettepe Univ, Dept Engn Phys, TR-06532 Ankara, Turkey

[2] Ankara Univ, Dept Chem, TR-06100 Ankara, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S010827019800835X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Cd{Cu(CH3CO2)(C17H16N2O2)}(2)].- C4H8O2, is a linear hetero-trinuclear complex with a central Cd-II ion and lies on an inversion centre. This central Cd-II ion has an irregular octahedral coordination. The coordination around the Cd-II ion involves four O atoms from two N,N'-bis(salicylidene)- 1,3-propane-diaminato (SALPD(2-)) and two acetate ligands. The terminal Cu-II ions have an irregular square-pyramidal coordination. The coordination of the terminal Cu-II atom is provided by the two O and two N atoms from an SALPD(2-) ligand and one O atom from an acetate Ligand. The Cd ... Cu bridging distance is 3.244(3) Angstrom.

引用

页码：1787 / 1790

页数：4

共 9 条

[1]

*ENR, 1993, CAD 4 EXPRESS VERS 1

[2] A linear trinuclear NiII-MnII-NiII complex with a μ-acetato bridge:: Bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato] (N,N-dimethylformamide)nickel(II)}manganese(II) [J].