A novel eight-membered Cu4I4 ring supported by sulfur atoms of an M(mnt)2 moiety:: syntheses and crystal structures of (NBun4)2[M(mnt)2Cu4I4] (M = Ni, Pd, Pt;: mnt = 1,2-dicyano-1,2-ethylenedithiolato) with doubly-bridged one-dimensional chain structures

被引：34

作者：

Sugimoto, K

Kuroda-Sowa, T ^{[1
]}

Maekawa, M

Munakata, M

机构：

[1] Kinki Univ, Dept Chem, Osaka 5778502, Japan

[2] Kinki Univ, Sci & Technol Res Inst, Osaka 5778502, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 05期

关键词：

D O I：

10.1039/a809708i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystal structure analyses of the title compounds revealed that they have almost the same structure with a novel eight-membered Cu4I4 ring supported by an M(mnt)(2) moiety, two cyano groups out of the four of which coordinate to two copper(I) ions in neighboring molecules, resulting in the formation of a unique doubly-bridged one-dimensional chain structure.

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页码：455 / 456

页数：2

相关论文

共 19 条

[1] A STUDY OF THE ONE-DIMENSIONAL CONDUCTOR LI0.75[PT(S2C2(CN)2)2].2H2O [J].

AHMAD, MM ;

UNDERHILL, AE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (06) :1065-1068

[2] SYSTEMATIC ANALYSIS OF STRUCTURAL DATA AS A RESEARCH TECHNIQUE IN ORGANIC-CHEMISTRY [J].

ALLEN, FH ;

KENNARD, O ;

TAYLOR, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (05) :146-153

[3] ELECTRONIC STRUCTURES OF SQUARE-PLANAR METAL COMPLEXES .2. COMPLEXES OF MALEONITRILEDITHIOLATE WITH COPPER(2) NICKEL)2) PALLADIUM)2) + PLATINUM)2) [J].

BILLIG, E ;

WATERS, JH ;

GRAY, HB ;

BERNAL, I ;

WILLIAMS, R .

INORGANIC CHEMISTRY, 1964, 3 (05) :663-&

[4] MOLECULES WITH AN M4X4 CORE .2. X-RAY CRYSTALLOGRAPHIC DETERMINATION OF MOLECULAR-STRUCTURE OF TETRAMERIC TRIPHENYLPHOSPHINECOPPER(I) BROMIDE IN CRYSTALLINE [PPH3CUBR]4.2CHCL3 [J].

CHURCHILL, MR ;

KALRA, KL .

INORGANIC CHEMISTRY, 1974, 13 (06) :1427-1434

[5] MOLECULES WITH AN M4X4 CORE .1. CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAMERIC TRIPHENYLPHOSPHINECOPPER(I) CHLORIDE, A CUBANE-LIKE MOLECULE, INCLUDING LOCATION AND REFINEMENT OF ALL HYDROGEN-ATOMS [J].

CHURCHILL, MR ;

KALRA, KL .

INORGANIC CHEMISTRY, 1974, 13 (05) :1065-1071

[6] Intermolecular interactions in the molecular ferromagnetic NH4Ni(mnt)(2)center dot H2O [J].

Coomber, AT ;

Beljonne, D ;

Friend, RH ;

Bredas, JL ;

Charlton, A ;

Robertson, N ;

Underhill, AE ;

Kurmoo, M ;

Day, P .

NATURE, 1996, 380 (6570) :144-146

[7] METAL-COMPLEXES AS LIGANDS .4. STRUCTURES OF BIS[BIS(TRIPHENYLPHOSPHINE)SILVER(I)] BIS(1,2-DICYANO-1,2-ETHYLENEDITHIOLATO)NICKELATE(II), [AG(P(C6H5)3)2]2NI(S2C2(CN)2)2, AND OF BIS[BIS(TRIPHENYLPHOSPHINE)SILVER(I)] BIS(1,1-DICYANO-2,2-ETHYLENEDITHIOLATO)NICKELATE(II), [AG(P(C6H5)3)2]2NI(S2C=C(CN)2)2 [J].

COUCOUVANIS, D ;

BAENZIGER, NC ;

JOHNSON, SM .

INORGANIC CHEMISTRY, 1974, 13 (05) :1191-1199

[8] MIXED-METAL COMPLEXES OF GROUP-10 AND GROUP-11 ELEMENTS - THE STRUCTURE AND PROPERTIES OF [M(MNT)(2)(AG(PR(3))(2))(2)] (M=NI, PD, PT MNT(2-)=MALEONITRILEDITHIOLATE) [J].

EBIHARA, M ;

TSUCHIYA, M ;

YAMADA, M ;

TOKORO, K ;

KAWAMURA, T .

INORGANICA CHIMICA ACTA, 1995, 231 (1-2) :35-43

[9] LEWIS-BASE ADDUCTS OF GROUP-11 METAL(I) COMPOUNDS .42. [CU4X4L4] CUBANE CLUSTERS, L = HINDERED N-BASE LIGAND - SYNTHESIS AND STRUCTURE OF THE L = 2-(DIPHENYLMETHYL)PYRIDINE COMPLEXES (X = CL, BR, I) [J].

ENGELHARDT, LM ;

HEALY, PC ;

KILDEA, JD ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1989, 42 (01) :107-113

[10]

HAKANSSON M, 1992, INORG CHEM, V31, P5389