The Use of Carbon Dioxide (CO2) as a Building Block in Organic Synthesis from an Industrial Perspective

被引：294

作者：

Dabral, Saumya ^{[1
]}

Schaub, Thomas ^{[1
,2
]}

机构：

[1] Catalysis Res Lab CaRLa, Neuenheimer Feld 584, D-69120 Heidelberg, Germany

[2] BASF SE, Synth & Homogeneous Catalysis, Carl Bosch Str 38, D-67056 Ludwigshafen, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2019年 / 361卷 / 02期

关键词：

applications; carbon dioxide; catalysis; industrial chemistry; organic synthesis; ALKYLIDENE CYCLIC CARBONATES; PALLADIUM-CATALYZED SYNTHESIS; KOLBE-SCHMITT REACTION; DIMETHYL CARBONATE; SELECTIVE SYNTHESIS; FORMIC-ACID; PROPARGYL ALCOHOLS; DIRECT METHYLATION; TERMINAL ALKYNES; DIRECT CARBOXYLATION;

D O I：

10.1002/adsc.201801215

中图分类号：

O69 [应用化学];

学科分类号：

070301 [无机化学];

摘要：

The use of carbon dioxide (CO2) as a building block in organic synthesis is a topic of high interest. We here reflect from an industrial perspective, which of the approaches may have the potential to be applied in the near future in industrial organic synthesis on a significant scale. Drawbacks to overcome and challenges to be addressed are also discussed in this critical review. This review focuses on systems providing a high atom-efficiency and which could be competitive to other state-of-the art syntheses.

引用

页码：223 / 246

页数：24

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