Lightwave has attractive characteristics such as spatial parallelism, temporal rapidity in signal processing, and frequency band vastness. In particular, the vast carrier frequency bandwidth promises novel information processing. In this paper, we propose a novel optical logic gate that learns multiple functions at frequencies different from one another, and analyze the frequency-domain multiplexing ability in the learning based on complex-valued Hebbian rule. We evaluate the averaged error function values in the learning process and the error probabilities in the realized logic functions. We investigate optimal learning parameters as well as performance dependence on the number of learning iterations and the number of parallel paths per neuron. Results show a trade-off among the learning parameters such as learning time constant and learning gain. We also find that when we prepare 10 optical path differences and conduct 200 learning iterations, the error probability completely decreases to zero in a three-function multiplexing case. However, at the same time, the error probability is tolerant of the path number. That is, even if the path number is reduced by half, error probability is found almost zero. The results can be useful to determine neural parameters for future optical neural network systems and devices that utilize the vast frequency bandwidth for frequency-domain multiplexing.