Investigation of the CO+NO reaction over the Cu(001) surface

被引：13

作者：

Godowski, PJ ^{[1
]}

Onsgaard, J

Gagor, A

Kondys, M

Li, ZS

机构：

[1] Univ Wroclaw, Inst Phys Expt, PL-50204 Wroclaw, Poland

[2] Aalborg Univ, Dept Phys & Nanotechnol, DK-9220 Aalborg, Denmark

[3] Polish Acad Sci, W Trzebiatowski Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland

[4] Aarhus Univ, Inst Phys & Astron, DK-8000 Aarhus, Denmark

来源：

CHEMICAL PHYSICS LETTERS | 2005年 / 406卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2005.03.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Coadsorption of NO + CO and CO + NO on Cu(001) at 115 K was investigated by valence band and core-level photoetectron spectroscopy based on the use of synchrotron radiation (SR-PS). Site exchange between NO and CO takes place when a CO saturated Cu(001) surface is exposed to NO. Both molecular and dissociated NO are observed on the surface. The effect of heating to 300 K was followed. The opposite adsorption sequence, CO exposure of the Cu(001) surface with preadsorbed NO, results in oxidation of CO and bonding Of CO2. Heating to 300 K causes desorption of the adsorbed CO2, NO and N. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：441 / 445

页数：5

共 24 条

[1] THE INTERACTION OF NO, O-2 AND CO WITH CU(100) AND CU(110) [J].

BALKENENDE, AR ;

DENDAAS, H ;

HUISMAN, M ;

GIJZEMAN, OLJ ;

GEUS, JW .

APPLIED SURFACE SCIENCE, 1991, 47 (04) :341-353

[2] CO dissociation on K-modified Cu(112) and Cu(117) [J].

Bech, L ;

Onsgaard, J ;

Hoffmann, SV ;

Godowski, PJ .

SURFACE SCIENCE, 2001, 482 :243-249

[3] NO chemisorption and reactions on metal surfaces: A new perspective [J].

Brown, WA ;

King, DA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (12) :2578-2595

[4] The development of a new concept: the role of oxygen transients, defect and precursor states in surface reactions [J].

Carley, AF ;

Davies, PR ;

Roberts, MW .

CATALYSIS LETTERS, 2002, 80 (1-2) :25-34

[5] Photoemission and high resolution electron energy loss spectroscopy study of CO/K/Cu(110) [J].

Christensen, SV ;

Nerlov, J ;

Godowski, PJ ;

Onsgaard, J .

JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (23) :9613-9619

[6]

Conny JM, 1998, SURF INTERFACE ANAL, V26, P939, DOI 10.1002/(SICI)1096-9918(199811)26:12<939::AID-SIA441>3.0.CO

[7]

2-V

[8] CO2 ADSORPTION AND REACTION ON FE(111) - AN ANGLE RESOLVED PHOTOEMISSION (ARUPS) STUDY [J].

FREUND, HJ ;

BEHNER, H ;

BARTOS, B ;

WEDLER, G ;

KUHLENBECK, H ;

NEUMANN, M .

SURFACE SCIENCE, 1987, 180 (2-3) :550-564

[9] Surface chemistry of carbon dioxide [J].

Freund, HJ ;

Roberts, MW .

SURFACE SCIENCE REPORTS, 1996, 25 (08) :225-273

[10] Photoemission study of CO2 adsorbed on K/Cu(110).: Analysis of adsorbate induced structures [J].

Godowski, PJ ;

Onsgaard, J ;

Hoffmann, SV ;

Nerlov, J .

ACTA PHYSICA POLONICA A, 1999, 95 (03) :423-431

← 1 2 3 →