Impedance spectroscopy at interfaces of metals and aqueous solutions - Surface roughness, CPE and related issues

被引：247

作者：

Pajkossy, T ^{[1
]}

机构：

[1] Hungarian Acad Sci, Chem Res Ctr, Inst Mat & Environm Chem, H-1525 Budapest, Hungary

来源：

SOLID STATE IONICS | 2005年 / 176卷 / 25-28期

关键词：

interfacial impedance; surface roughness; capacitance dispersion; constant phase element; non-Faradaic process; adsorption process; porous electrode; fractal;

D O I：

10.1016/j.ssi.2004.06.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The interfacial impedance of solid electrodes deviates from that of an ideal capacitor even in the complete absence of Faradaic reactions; the deviation is usually larger on rough electrodes than on smooth ones. The origin of this deviation is discussed; the roles of atomic scale roughness and of the adsorption processes are analyzed. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1997 / 2003

页数：7

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