Intedigitated p-n junction: a route to improve the efficiency in organic photovoltaic cells

被引:13
作者
Murgia, M [1 ]
Biscarini, F [1 ]
Cavallini, M [1 ]
Taliani, C [1 ]
Ruani, G [1 ]
机构
[1] CNR, Ist Spettroscopia Mol, I-40129 Bologna, Italy
关键词
solar cells; hetero-junctions; polycrystalline thin films; fullerenes and derivatives; evaporation and sublimation;
D O I
10.1016/S0379-6779(00)01167-X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The short mean free path of excitons photogenerated in real organic photovoltaic (O-PV) cell strongly reduces the effective active volume of a device. In fact, in a p-n junction O-PV structure, only those excitons that are formed close to the interface between the n-type and the p-type materials are able to dissociate giving free carriers. One of the possible routes to increase the efficiency of a O-PV, is to extend the surface area of the junction. Within this perspective, an interdigitated structure has been obtained by controlled differential co-sublimation in UHV of C-60 (n-type) and Zn-phthalocyanine (ZnPc, p-type). Spectroscopic investigation evidenced that the increase of the photovoltaic efficiency is related also to the existence of a weak charge transfer (CT) absorption state in the near infrared region.
引用
收藏
页码:1533 / 1534
页数:2
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