Synthesis of thermosensitive PNIPAM-co-MBAA nanotubes by atom transfer radical polymerization within a porous membrane

被引：61

作者：

Cui, Y ^{[1
]}

Tao, C ^{[1
]}

Zheng, SP ^{[1
]}

He, Q ^{[1
]}

Ai, SF ^{[1
]}

Li, JB ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci,Int Joint Lab, Key Lab Colloid & Interface Sci, Beijing 100080, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2005年 / 26卷 / 19期

关键词：

atom transfer radical polymerization (ATRP); fluid AFM; nanotubes; templates; thermosensitive polymer;

D O I：

10.1002/marc.200500373

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Thermosensitive polymer nanotubes can be fabricated within an aminopropylsilane-modified porous anodic aluminum oxide membrane by surface-initiated atom transfer radical polymerization (ATRP) followed by template removal. DSC experiments prove that the synthesized PNIPAM-co-MBAA copolymer nanotubes have a reversible thermosensitive behavior. The temperature-induced changes in dimension and shape of the nanotubes were studied by AFM in real time in an aqueous environment. It indicates that the nanotubes undergo a shape alteration from an "ellipse" to ''circular" shape in water upon heating to LCST or above.

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收藏

页码：1552 / 1556

页数：5

相关论文

共 45 条

[1] Highly flexible polyelectrolyte nanotubes [J].

Ai, SF ;

Lu, G ;

He, Q ;

Li, JB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) :11140-11141

[2] Thermal response of poly(N-isopropylacrylamide) brushes probed by surface plasmon resonance [J].

Balamurugan, S ;

Mendez, S ;

Balamurugan, SS ;

O'Brien, MJ ;

López, GP .

LANGMUIR, 2003, 19 (07) :2545-2549

[3] Preparation of polymeric micro- and nanostructures using a template-based deposition method [J].

Cepak, VM ;

Martin, CR .

CHEMISTRY OF MATERIALS, 1999, 11 (05) :1363-1367

[4] Temperature-switchable vapor sensor materials based on N-isopropylacrylamide and calcium chloride [J].

Chen, JH ;

Yoshida, M ;

Maekawa, Y ;

Tsubokawa, N .

POLYMER, 2001, 42 (23) :9361-9365

[5] Bacterial adsorption to thermoresponsive polymer surfaces [J].

Cunliffe, D ;

Smart, CA ;

Tsibouklis, J ;

Young, S ;

Alexander, C ;

Vulfson, EN .

BIOTECHNOLOGY LETTERS, 2000, 22 (02) :141-145

[6] Reversible control of free energy and topography of nanostructured surfaces [J].

Fu, Q ;

Rao, GVR ;

Basame, SB ;

Keller, DJ ;

Artyushkova, K ;

Fulghum, JE ;

López, GP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (29) :8904-8905

[7] Thermoresponsive poly(N-isopropylacrylamide) copolymers:: Contact angles and surface energies of polymer films [J].

Gilcreest, VP ;

Carroll, WM ;

Rochev, YA ;

Blute, I ;

Dawson, KA ;

Gorelov, AV .

LANGMUIR, 2004, 20 (23) :10138-10145

[8] Photo-cross-linkable PNIPAAm copolymers. 4. Effects of copolymerization and cross-linking on the volume-phase transition in constrained hydrogel layers [J].

Harmon, ME ;

Kuckling, D ;

Pareek, P ;

Frank, CW .

LANGMUIR, 2003, 19 (26) :10947-10956

[9] VOLUME PHASE-TRANSITION IN A NONIONIC GEL [J].

HIROKAWA, Y ;

TANAKA, T .

JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (12) :6379-6380

[10] VOLUME-PHASE TRANSITIONS OF IONIZED N-ISOPROPYLACRYLAMIDE GELS [J].

HIROTSU, S ;

HIROKAWA, Y ;

TANAKA, T .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (02) :1392-1395

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