Synthesis of semiaromatic polyimides from aromatic diamines containing adamantyl units and alicyclic dianhydrides

被引：57

作者：

Watanabe, Y ^{[1
]}

Shibasaki, Y ^{[1
]}

Ando, S ^{[1
]}

Ueda, M ^{[1
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 01期

关键词：

adamantane; biadamantane; polyimides; thermal properties; refractive index;

D O I：

10.1002/pola.10990

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We prepared new semiaromatic polyimides from alicyclic dianhydrides and aromatic diamines containing adamantyl and biadamantyl units. Polycondensations were performed in 1-methyl-2-pyrrolidinone at room temperature for 7 h and then 80 degreesC for 23 h, giving poly(amic acid)s with inherent viscosities up to 0.58 dL/g. Poly(amic acid)s were converted to corresponding poly(imide)s by thermal treatment. Poly(imide)s showed relatively high thermal stability (5% weight loss around 450 degreesC) and low dielectric constants (2.69-2.79). (C) 2003 Wiley Periodicals, Inc.

引用

收藏

页码：144 / 150

页数：7

相关论文

共 23 条

[1] CHAIN ORIENTATION AND ANISOTROPIES IN OPTICAL AND DIELECTRIC-PROPERTIES IN THIN-FILMS OF STIFF POLYIMIDES [J].

BOESE, D ;

LEE, H ;

YOON, DY ;

SWALEN, JD ;

RABOLT, JF .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1992, 30 (12) :1321-1327

[2] Low dielectric constants of soluble polyimides derived from the novel 4,9-bis[4-(4-aminophenoxy)phenyl]diamantane [J].

Chern, YT ;

Shiue, HC .

MACROMOLECULES, 1997, 30 (19) :5766-5772

[3] Low dielectric constants of soluble polyimides based on adamantane [J].

Chern, YT ;

Shiue, HC .

MACROMOLECULES, 1997, 30 (16) :4646-4651

[4] High subglass transitions appearing in the rigid polyimides derived from the novel 1,6-bis(4-aminophenyl)diamantane [J].

Chern, YT .

MACROMOLECULES, 1998, 31 (06) :1898-1905

[5] High subglass transition temperatures and low dielectric constants of polyimides derived from 4,9-bis(4-aminophenyl)diamantane [J].

Chern, YT ;

Shiue, HC .

CHEMISTRY OF MATERIALS, 1998, 10 (01) :210-216

[6] Low dielectric constant polyimides derived from novel 1,6-bis[4-(4-aminophenoxy)phenyl]diamantane [J].

Chern, YT .

MACROMOLECULES, 1998, 31 (17) :5837-5844

[7] Low dielectric constant polyimides derived from 1,3-bis(4-aminophenyl)adamantane [J].

Chern, YT ;

Shiue, HC .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 1998, 199 (06) :963-969

[8]

Ghosh M. K., 1996, POLYIMIDES FUNDAMENT

[9] SOLUBLE POLYIMIDES WITH POLYALICYCLIC STRUCTURE .1. POLYIMIDES FROM BICYCLO[2.2.2]OCT-7-ENE-2-EXO,3-EXO,5-EXO,6-EXO-TETRACARBOXYLIC 2,3/5,6-DIANHYDRIDES [J].

ITAMURA, S ;

YAMADA, M ;

TAMURA, S ;

MATSUMOTO, T ;

KUROSAKI, T .

MACROMOLECULES, 1993, 26 (14) :3490-3493

[10] POLYIMIDES WITH ALICYCLIC DIAMINES .2. HYDROGEN ABSTRACTION AND PHOTO-CROSS-LINKING REACTIONS OF BENZOPHENONE-TYPE POLYIMIDES [J].

JIN, Q ;

YAMASHITA, T ;

HORIE, K .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (03) :503-511